Ren, S.; Bojdys, M. J.; Dawson, R.; Laybourn, A.; Khimyak, Y. Z.; Adams, D. J.; Cooper,* A. I. Advanced Materials 2012, 24, 2357-2361.
Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g-1 and exceptional CO2 capacities (up to 4.17 mmol g-1).
DOI: 10.1002/adma.201200751 [Download]
This is the pre-peer reviewed version of the following article: Ren, S.; Bojdys, M. J.; Dawson, R.; Laybourn, A.; Khimyak, Y. Z.; Adams, D. J.; Cooper, A. I. Advanced Materials 2012, 24, 2357-2361, which has been published in final form at [DOI: 10.1002/adma.201200751].