Porous, Fluorescent, Covalent Triazine-Based Frameworks Via Room-Temperature and Microwave-Assisted Synthesis

Ren, S.; Bojdys, M. J.; Dawson, R.; Laybourn, A.; Khimyak, Y. Z.; Adams, D. J.; Cooper,* A. I. Advanced Materials 2012, 24, 2357-2361.

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Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g-1 and exceptional CO2 capacities (up to 4.17 mmol g-1).

DOI: 10.1002/adma.201200751 [Download]

This is the pre-peer reviewed version of the following article: Ren, S.; Bojdys, M. J.; Dawson, R.; Laybourn, A.; Khimyak, Y. Z.; Adams, D. J.; Cooper, A. I. Advanced Materials 2012, 24, 2357-2361, which has been published in final form at [DOI: 10.1002/adma.201200751].